Adsorption of dianionic surfactants based on amino acids at different surfaces studied by QCM-D and SPR

The adsorption of three dicarboxylic amino acid-based surfactants, disodium N-lauroylaminomalonate, disodium N-lauroylaspartate, and disodium N-lauroylglutamate, has been studied by surface plasmon resonance (SPR) and the quartz crystal microbalance with dissipation monitoring (QCM-D). These surfact...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1991. - 26(2010), 13 vom: 06. Juli, Seite 10935-42
1. Verfasser: Bordes, Romain (VerfasserIn)
Weitere Verfasser: Tropsch, Jürgen, Holmberg, Krister
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2010
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Amino Acids Surface-Active Agents Quartz 14808-60-7 Gold 7440-57-5 Silicon Dioxide 7631-86-9 Durapatite 91D9GV0Z28
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520 |a The adsorption of three dicarboxylic amino acid-based surfactants, disodium N-lauroylaminomalonate, disodium N-lauroylaspartate, and disodium N-lauroylglutamate, has been studied by surface plasmon resonance (SPR) and the quartz crystal microbalance with dissipation monitoring (QCM-D). These surfactants have high cmc values, which means that the unimer concentration is high at the plateau value of adsorption. This gives rise to a considerable "bulk effect", which must be deducted from the observed value in order to obtain the true value of the adsorbed amount. In this article, we show how this can be done for the QCM-D technique. Adsorption is studied on silica, gold, gold hydrophobized by a self-assembled layer of an alkane thiol, and hydroxyapatite. Adsorption on hydroxyapatite differs very much among the three surfactants, with the aspartate derivative giving the strongest and the glutamate giving the weakest adsorption. This difference is explained as the difference in ability of the dicarboxylic amphiphiles to chelate calcium in the crystal lattice 
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700 1 |a Tropsch, Jürgen  |e verfasserin  |4 aut 
700 1 |a Holmberg, Krister  |e verfasserin  |4 aut 
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