A novel approach for preparation of micrometer-sized, monodisperse dimple and hemispherical polystyrene particles
Micrometer-sized, monodisperse dimple and hemispherical polystyrene (PS) particles were successfully prepared by heating (55-70 degrees C) of spherical PS particles dispersed in methanol/water media (40/60 to 80/20, w/w) in the presence of decane droplets, and subsequent cooling down to room tempera...
| Veröffentlicht in: | Langmuir : the ACS journal of surfaces and colloids. - 1985. - 26(2010), 6 vom: 16. März, Seite 3848-53 |
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| Weitere Verfasser: | , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2010
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| Zugriff auf das übergeordnete Werk: | Langmuir : the ACS journal of surfaces and colloids |
| Schlagworte: | Journal Article |
| Zusammenfassung: | Micrometer-sized, monodisperse dimple and hemispherical polystyrene (PS) particles were successfully prepared by heating (55-70 degrees C) of spherical PS particles dispersed in methanol/water media (40/60 to 80/20, w/w) in the presence of decane droplets, and subsequent cooling down to room temperature. Decane was absorbed by the PS particles during the heating process. Decane-absorbed PS particles phase-separated into PS and decane phases in the inside during the cooling process, and eventually dimple and/or hemispherical particles were formed by removal of the decane phase from phase-separated PS/decane particles by evaporation. The size of the dimple, which is determined by the volume of decane phase-separated from decane-absorbed PS particles during the cooling process, increased with increases in the heating temperature and the methanol content |
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| Beschreibung: | Date Completed 01.06.2010 Date Revised 10.03.2010 published: Print Citation Status PubMed-not-MEDLINE |
| ISSN: | 1520-5827 |
| DOI: | 10.1021/la903309t |