The uptake and release of cationic surfactant from polyampholyte microgel particles in dispersion and as an adsorbed monolayer

The use of novel polyampholyte microgel particles for the controlled absorption and release of a cationic surfactant has been investigated. The addition of cetylpyridinium chloride (CPC) to aqueous dispersions of poly(2-diethylamino)ethyl methacrylate-co-methacrylic acid (DEAEM-co-MAAc) microgel par...

Description complète

Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 25(2009), 17 vom: 01. Sept., Seite 9677-83
Auteur principal: Bradley, Melanie (Auteur)
Autres auteurs: Liu, Dan, Keddie, Joseph L, Vincent, Brian, Burnett, Gary
Format: Article en ligne
Langue:English
Publié: 2009
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article
LEADER 01000caa a22002652c 4500
001 NLM190908351
003 DE-627
005 20250210173714.0
007 cr uuu---uuuuu
008 231223s2009 xx |||||o 00| ||eng c
024 7 |a 10.1021/la900917v  |2 doi 
028 5 2 |a pubmed25n0636.xml 
035 |a (DE-627)NLM190908351 
035 |a (NLM)19705880 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Bradley, Melanie  |e verfasserin  |4 aut 
245 1 4 |a The uptake and release of cationic surfactant from polyampholyte microgel particles in dispersion and as an adsorbed monolayer 
264 1 |c 2009 
336 |a Text  |b txt  |2 rdacontent 
337 |a ƒaComputermedien  |b c  |2 rdamedia 
338 |a ƒa Online-Ressource  |b cr  |2 rdacarrier 
500 |a Date Completed 03.11.2009 
500 |a Date Revised 26.08.2009 
500 |a published: Print 
500 |a Citation Status PubMed-not-MEDLINE 
520 |a The use of novel polyampholyte microgel particles for the controlled absorption and release of a cationic surfactant has been investigated. The addition of cetylpyridinium chloride (CPC) to aqueous dispersions of poly(2-diethylamino)ethyl methacrylate-co-methacrylic acid (DEAEM-co-MAAc) microgel particles has been studied with respect to CPC concentration and solution pH. CPC was found to absorb into the polyampholyte microgel particles, resulting in reduced hydrodynamic diameter and electrophoretic mobility, when added to microgel dispersion at pH 11. Strong desorption could be induced by switching the pH from 11 to 3, with most of the desorption occurring in the region of the isoelectric pH of the particles. The properties of surface-adsorbed monolayers of polyampholyte microgel particles were also investigated, both in the presence and absence of CPC. The substrate surface charge was found to influence the swelling profile of the adsorbed microgel monolayers. The interaction of CPC surfactant with monolayers of adsorbed microgel particles shows strong correlations with the interaction of CPC surfactant with microgel particles in dispersion 
650 4 |a Journal Article 
700 1 |a Liu, Dan  |e verfasserin  |4 aut 
700 1 |a Keddie, Joseph L  |e verfasserin  |4 aut 
700 1 |a Vincent, Brian  |e verfasserin  |4 aut 
700 1 |a Burnett, Gary  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1985  |g 25(2009), 17 vom: 01. Sept., Seite 9677-83  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnas 
773 1 8 |g volume:25  |g year:2009  |g number:17  |g day:01  |g month:09  |g pages:9677-83 
856 4 0 |u http://dx.doi.org/10.1021/la900917v  |3 Volltext 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 25  |j 2009  |e 17  |b 01  |c 09  |h 9677-83