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231223s2008 xx |||||o 00| ||eng c |
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|a 10.1021/la7040295
|2 doi
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|a pubmed25n0601.xml
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|a DE-627
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|a eng
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| 100 |
1 |
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|a Liu, Jui-Hsiang
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Fabrication and characterization of a novel inclusion complex of chiral monomer derived from (+)-camphor with beta-cyclodextrins
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|c 2008
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 15.08.2008
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|a Date Revised 09.07.2008
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a In order to develop a highly ordered polymer dopant to improve the physical properties of polymer materials for microsystems, a novel supramolecular inclusion complex (IC) of chiral bornyl 4-(6-acryloyloxyhexyloxy) phenyl-4'-benzoate ( BAPB) threaded with beta-cyclodextrins (beta-CDs) was synthesized. The inclusion complex was identified using Fourier transform infrared (FTIR), UV, 13C cross-polarization/magic-angle spinning (CP/MAS) NMR, 1H NMR, and X-ray diffraction (XRD). The construction of the fibrous self-assembled inclusion complex was confirmed using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. The highly ordered polymerized inclusion complex beta-CD-BAPB revealed significant birefringence and was confirmed using polarized optical microscopy (POM). Polymerization of self-assembled nanofibrous monomers with methyl methacrylate was carried out, and the distribution of the nanofibers in the polymer matrix was confirmed using POM. This investigation demonstrates a novel method for the fabrication of polymeric nanofibers with highly ordered, self-assembled functional monomers. The polymeric nanofibers are expected to improve the physical properties of polymer films in the field of microelectric and micromachine systems (MEMS)
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|a Journal Article
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|a Research Support, Non-U.S. Gov't
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|a beta-Cyclodextrins
|2 NLM
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|a Camphor
|2 NLM
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| 650 |
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|a 76-22-2
|2 NLM
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| 700 |
1 |
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|a Hung, Hsien-Jung
|e verfasserin
|4 aut
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| 700 |
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|a Harada, Akira
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1985
|g 24(2008), 14 vom: 15. Juli, Seite 7442-9
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnas
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| 773 |
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|g volume:24
|g year:2008
|g number:14
|g day:15
|g month:07
|g pages:7442-9
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|u http://dx.doi.org/10.1021/la7040295
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