Surfactant-free "emulsions" generated by freeze-thaw

The stability ofsurfactantless dispersions of surface chemically pure alkanes was studied in the presence and absence of dissolved gas. It was found that simply freezing and thawing a sample of oil and water results in a dispersion. A mechanism based on fingering of the insoluble oil into the aqueou...

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Détails bibliographiques
Publié dans:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 20(2004), 14 vom: 06. Juli, Seite 5673-8
Auteur principal: Burnett, Gary R (Auteur)
Autres auteurs: Atkin, Rob, Hicks, Stuart, Eastoe, Julian
Format: Article
Langue:English
Publié: 2004
Accès à la collection:Langmuir : the ACS journal of surfaces and colloids
Sujets:Journal Article
Description
Résumé:The stability ofsurfactantless dispersions of surface chemically pure alkanes was studied in the presence and absence of dissolved gas. It was found that simply freezing and thawing a sample of oil and water results in a dispersion. A mechanism based on fingering of the insoluble oil into the aqueous phase, due to local surface tension gradients, followed by separation and nucleation into droplets, is proposed to account for this observation
Description:Date Completed 20.03.2007
Date Revised 07.02.2006
published: Print
Citation Status PubMed-not-MEDLINE
ISSN:1520-5827