Mixtures of mucin and oppositely charged surfactant aggregates with varying charge density. Phase behavior, association, and dynamics

The nonionic surfactant Tween80 is a commonly used excipient in drug formulations containing an active substance with low aqueous solubility. Model drug vehicles with varying charge density were obtained by mixing Tween80 (PS-80) with the cationic surfactant Tetradecyltrimethylammonium chloride (TTA...

Ausführliche Beschreibung

Bibliographische Detailangaben
Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 21(2005), 16 vom: 02. Aug., Seite 7097-104
1. Verfasser: Lafitte, Géraldine (VerfasserIn)
Weitere Verfasser: Thuresson, Krister, Söderman, Olle
Format: Aufsatz
Sprache:English
Veröffentlicht: 2005
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article Research Support, Non-U.S. Gov't Cations Micelles Mucins Polymers Polysorbates Quaternary Ammonium Compounds Surface-Active Agents Trimethyl Ammonium Compounds mehr... tetradecyltrimethylammonium Y3IR7RCT6J
LEADER 01000caa a22002652c 4500
001 NLM156774674
003 DE-627
005 20250206135422.0
007 tu
008 231223s2005 xx ||||| 00| ||eng c
028 5 2 |a pubmed25n0523.xml 
035 |a (DE-627)NLM156774674 
035 |a (NLM)16042429 
040 |a DE-627  |b ger  |c DE-627  |e rakwb 
041 |a eng 
100 1 |a Lafitte, Géraldine  |e verfasserin  |4 aut 
245 1 0 |a Mixtures of mucin and oppositely charged surfactant aggregates with varying charge density. Phase behavior, association, and dynamics 
264 1 |c 2005 
336 |a Text  |b txt  |2 rdacontent 
337 |a ohne Hilfsmittel zu benutzen  |b n  |2 rdamedia 
338 |a Band  |b nc  |2 rdacarrier 
500 |a Date Completed 22.06.2006 
500 |a Date Revised 01.12.2018 
500 |a published: Print 
500 |a Citation Status MEDLINE 
520 |a The nonionic surfactant Tween80 is a commonly used excipient in drug formulations containing an active substance with low aqueous solubility. Model drug vehicles with varying charge density were obtained by mixing Tween80 (PS-80) with the cationic surfactant Tetradecyltrimethylammonium chloride (TTAC), thus forming mixed micelles. The micelles were mixed with the negatively charged polyelectrolyte mucin, which is a component in the protective mucus layer covering epithelial cell linings. Depending on the composition of the mixture, complex-formation could be followed by precipitation. Using X-ray diffraction, it was found that the precipitate contained a lamellar phase with properties sensitive to the proportion of PS-80. Higher amounts of PS-80 were found to oppose phase separation. Further analysis in the one-phase region, or alternatively of the supernatant of two-phase samples, by (1)H NMR, HPLC, and diffusion measurements with PGSE-NMR led to the conclusions that at low proportion of PS-80 aggregates composed of mixed (PS-80 and TTAC) micelles and mucin were formed, whereas increased concentrations of PS-80 favored the dissolution of the precipitate and limited the interactions between mixed micelles and the polymer 
650 4 |a Journal Article 
650 4 |a Research Support, Non-U.S. Gov't 
650 7 |a Cations  |2 NLM 
650 7 |a Micelles  |2 NLM 
650 7 |a Mucins  |2 NLM 
650 7 |a Polymers  |2 NLM 
650 7 |a Polysorbates  |2 NLM 
650 7 |a Quaternary Ammonium Compounds  |2 NLM 
650 7 |a Surface-Active Agents  |2 NLM 
650 7 |a Trimethyl Ammonium Compounds  |2 NLM 
650 7 |a tetradecyltrimethylammonium  |2 NLM 
650 7 |a Y3IR7RCT6J  |2 NLM 
700 1 |a Thuresson, Krister  |e verfasserin  |4 aut 
700 1 |a Söderman, Olle  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Langmuir : the ACS journal of surfaces and colloids  |d 1985  |g 21(2005), 16 vom: 02. Aug., Seite 7097-104  |w (DE-627)NLM098181009  |x 1520-5827  |7 nnas 
773 1 8 |g volume:21  |g year:2005  |g number:16  |g day:02  |g month:08  |g pages:7097-104 
912 |a GBV_USEFLAG_A 
912 |a SYSFLAG_A 
912 |a GBV_NLM 
912 |a GBV_ILN_22 
912 |a GBV_ILN_350 
912 |a GBV_ILN_721 
951 |a AR 
952 |d 21  |j 2005  |e 16  |b 02  |c 08  |h 7097-104