Competitive transport of cadmium and lead through a natural porous medium : influence of the solid/liquid interface processes

Contaminated groundwater typically contains different metal contaminants which may compete with each other for the same adsorption sites. Understanding the fate of these micro-pollutants is of primary importance for the assessment of the risk associated with their dispersion in the environment and f...

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Veröffentlicht in:Water science and technology : a journal of the International Association on Water Pollution Research. - 1986. - 48(2003), 3 vom: 05., Seite 9-16
1. Verfasser: Bianchi, A (VerfasserIn)
Weitere Verfasser: Papini, M Petrangeli, Corsi, A, Behra, P, Beccari, M
Format: Aufsatz
Sprache:English
Veröffentlicht: 2003
Zugriff auf das übergeordnete Werk:Water science and technology : a journal of the International Association on Water Pollution Research
Schlagworte:Journal Article Soil Pollutants Water Pollutants Cadmium 00BH33GNGH Lead 2P299V784P
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245 1 0 |a Competitive transport of cadmium and lead through a natural porous medium  |b influence of the solid/liquid interface processes 
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520 |a Contaminated groundwater typically contains different metal contaminants which may compete with each other for the same adsorption sites. Understanding the fate of these micro-pollutants is of primary importance for the assessment of the risk associated with their dispersion in the environment and for the evaluation of the most appropriate remediation technology. In this regard, column techniques can be considered as useful tools both to perform transport experiments and to obtain equilibrium adsorption data without any perturbation of the actual solid/liquid interface. Cd and Pb monocomponent step column experiments were used to obtain adsorption isotherms on a natural aquifer material. A General Composite approach was used to define the equilibrium adsorption model characterized by two types of sites (ion-exchange and surface complexation sites). Coupling the adsorption model with the Advection-Dispersion equation (by IMPACT code) allowed us to well represent the monocomponent step experiments. The model was successfully used to predict the competitive Cd and Pb transport behaviour. Cd peaks of concentration due to Pb competition were experimentally observed and simulated by the model. This behaviour can be described only by an accurate modelling of the interaction and cannot be predicted by simple isotherms (such as Langmuir or Freundlich type) 
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650 7 |a Lead  |2 NLM 
650 7 |a 2P299V784P  |2 NLM 
700 1 |a Papini, M Petrangeli  |e verfasserin  |4 aut 
700 1 |a Corsi, A  |e verfasserin  |4 aut 
700 1 |a Behra, P  |e verfasserin  |4 aut 
700 1 |a Beccari, M  |e verfasserin  |4 aut 
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