Journal Article Na-ion batteries all‐solid‐state battery (ASSB) anode‐free battery argyrodite borohydride cryogenic microscopy electrolyte electrolytes inorganic solid electrolyte interfacial chemistry liquid metals lithium-metal batteries lithium‐metal batteries localized high‐concentration electrolytes long-term stability long‐term stability polyanion room temperature smart grid sodium metal batteries solid electrolyte interphase solid‐electrolyte interphase solid‐state battery solid‐state electrolyte (SE) solvation structure solvent mixtures sulfide electrolyte tetrahydrofuran time‐of‐flight secondary‐ion mass spectrometry